主管:中华人民共和国应急管理部
主办:应急管理部天津消防研究所
ISSN 1009-0029  CN 12-1311/TU

消防科学与技术 ›› 2023, Vol. 42 ›› Issue (4): 477-482.

• • 上一篇    下一篇

低温冷却对三元锂离子电池热失控抑制效果研究

张 鹏,苏金刚,贾伯岩,魏力强   

  1. (国网河北省电力公司电力科学研究院,河北 石家庄 050011)
  • 出版日期:2023-04-15 发布日期:2023-04-15
  • 作者简介:张 鹏(1993— ),男,河北邯郸人,国网河北省电力有限公司电力科学研究院电力设备技术中心电缆技术研究室工程师,主要从事电力电缆运维管理、状态评价以及电气试验等工作,河北省石家庄市裕华区富强大街32号,050011。
  • 基金资助:
    国网河北省电力有限公司科技项目(TSS2020-03)

Study on the effectiveness of cryogenic cooling on the prevention and control of thermal runaway of ternary lithium-ion battery

Zhang Peng, Su Jingang, Jia Boyan, Wei Liqiang   

  1. (State Grid Hebei Electric Power Research Institute, Hebei Shijiazhuang 050011, China)
  • Online:2023-04-15 Published:2023-04-15

摘要: 为了解决锂离子电池在储存、运输中的失火难题,提出采用低温控制预防锂离子电池热失控的方法,并开展了低温冷却作用下三元锂离子电池热失控试验。研究结果表明:低温冷却能够通过降低锂离子电池内部反应活性,削弱锂离子电池热失控后的能量释放,进而阻断电池组间的热失控链式传播;锂离子电池的温度越低,电池越难发生热失控,当温度降至-30 ℃以下时,被直接穿刺的电池也不会发生热失控;由于低温的影响,电池内部材料活性降低,电池内部的化学反应受到限制,电池在试验后的质量损失和释放的CO气体体积分数显著降低。

关键词: 锂离子电池, 低温冷却, 热失控, 储能

Abstract: In order to solve the fire problem in the storage and transportation of lithium-ion batteries, a method of preventing thermal runaway of lithium-ion batteries by low temperature control was proposed, and the thermal runaway test of ternary lithium-ion batteries under low temperature cooling was carried out. The results show that low-temperature cooling can reduce the internal reaction activity of lithium-ion batteries, weaken the energy release after thermal runaway of lithium-ion batteries, and then block the chain propagation of thermal runaway between battery packs; The lower the temperature of the lithium-ion battery, the more difficult it is to have thermal runaway. When the temperature drops below -30 ℃, the directly punctured battery will not have thermal runaway; Due to the influence of low temperature, the internal material activity of the battery is reduced, the chemical reaction inside the battery is limited, and the mass loss and CO volume fraction of the battery after the test are also significantly reduced.

Key words: lithium-ion battery, low temperature cooling, thermal runaway, energy storage