主管:中华人民共和国应急管理部
主办:应急管理部天津消防研究所
ISSN 1009-0029  CN 12-1311/TU

消防科学与技术 ›› 2025, Vol. 44 ›› Issue (5): 675-680.

• • 上一篇    下一篇

消防服污渍组分检测研究

董齐齐1, 于晞2, 俞川华3, 刘建立1   

  1. (1.江南大学 纺织科学与工程学院,江苏 无锡 214122; 2.南京海关纺织工业产品检测中心,江苏 无锡 214101; 3.上海赞瑞实业有限公司,上海 201318)
  • 收稿日期:2024-05-07 修回日期:2024-10-21 出版日期:2025-05-15 发布日期:2025-05-15
  • 作者简介:董齐齐,江南大学纺织科学与工程学院硕士研究生,主要从事消防服污渍吸附与解吸附理论与试验研究,江苏省无锡市滨湖区蠡湖大道1800号,214122。
  • 基金资助:
    天津市应用基础研究多元投入——城市消防项目(22JCQNJC01760)

Study on the detection of stain components in firefighting clothing

Dong Qiqi1, Yu Xi2, Yu Chuanhua3, Liu Jianli1   

  1. (1. College of Textile Science and Engineering, Jiangnan University, Wuxi Jiangsu 214122, China; 2. Textile Industrial Products Testing Center of Nanjing Customs District, Wuxi Jiangsu 214101, China; 3. Shanghai Zanray Industrial Co., Ltd., Shanghai 201318, China)
  • Received:2024-05-07 Revised:2024-10-21 Online:2025-05-15 Published:2025-05-15

摘要: 污渍组分检测是消防服科学洗消的重要基础,是开展消防员次生职业暴露防护的主要依据。为此,本研究采用丙酮、甲醇、三氯甲烷、正己烷和2%硝酸对消防服表面污渍进行萃取采集。然后,分别采用气相色谱-质谱联用技术(GC-MS)、液相色谱-串联质谱技术(LC-MS/MS)以及电感耦合等离子体质谱技术(ICP-MS)对萃取采集的污渍试样进行有机化合物、全氟和多氟烷基化合物(PFAS)以及重金属元素检测。试验结果表明共检出有机化合物59种,PFAS6种,重金属17种。

关键词: 消防服, 污渍, 有机污染物, PFAS, 重金属

Abstract: The detection of stains component is an important basis for the scientific washing and disinfection of firefighting uniforms, at the same time, it' s also the main basis for carrying out secondary occupational exposure protection for firefighters. For this purpose, this study will use acetone, methanol, trichloromethane, n-hexane, and 2% nitric acid to extract and collect surface stains on firefighting suits. In addition, gas chromatography-mass spectrometry (GC-MS), liquid chromatography-tandem mass spectrometry (LC-MS/MS), and inductively coupled plasma mass spectrometry (ICP-MS) were used to detect organic compounds, perfluoroalkyl compounds (PFAS), and heavy metal elements in the extracted stained samples. The experimental results showed that a total of 59 organic compounds, 6 PFASs, and 17 heavy metals were detected.

Key words: fire protective clothing, stain, organic pollutants, PFAS, heavy metals