磷系阻燃剂在透明防火涂料中的应用研究进展

消防科学与技术 ›› 2021, Vol. 40 ›› Issue (7): 1061-1064.

磷系阻燃剂在透明防火涂料中的应用研究进展

胡肖1，颜龙2，黄傲1，赵敏1，王学宝1，孙均利1，王霁1

1. 中国人民警察大学研究生学院，河北廊坊065000；2. 中南大学防灾科学与安全技术研究所，湖南长沙410075

出版日期:2021-07-15 发布日期:2021-07-15
作者简介:胡肖（1996-），女，中国人民警察大学硕士研究生，主要从事膨胀型透明防火涂料研究，河北省廊坊市安次区西昌路220 号，065000。
基金资助:
国家自然科学基金项目（51906261）；河北省高等学校科学技术研究项目（ZD2020408）

Progress in research and application of phosphorous flame retardants in transparent fire-retardant coatings

HU Xiao1，YAN Long2，HUANG Ao1， ZHAO Min1，WANG Xue-bao1， SUN Jun-li1，WANG Ji1

1. Graduate School, China People's Police University, Hebei Langfang 065000, China; 2. Institute of Disaster Prevention Science and Safety Technology, Central South University, Hunan Changsha 410075, China

Online:2021-07-15 Published:2021-07-15
Contact: 赵敏（1965-），男，中国人民警察大学侦察学院教授。

摘要/Abstract

摘要： 木结构建筑耐火等级低、火灾荷载大，一旦发生火灾将会造成严重的火灾事故，透明防火涂料因兼具优异的装饰性能被广泛用于增强木结构建筑的火灾安全。磷系阻燃剂具有环保、高效、低毒等优点，是透明防火涂料的主要组成部分。从磷酸酯类阻燃剂、磷-氮阻燃剂和复合磷系阻燃剂等方面，综述了磷系阻燃剂在透明防火涂料中的应用研究进展。指出开发出多功能改性磷系阻燃剂，实现磷系阻燃剂三源一体、有机无机复合、多种元素协效阻燃是未来透明防火涂料的发展趋势。

关键词: 透明防火涂料, 磷酸酯阻燃剂, 磷-氮阻燃剂, 复合磷系阻燃剂

Abstract: Wood-based structure has low fire resistance levels and large fire loads. Once a fire occurs, it will cause serious fire accidents. Transparent fire-retardant coatings are widely used to enhance the fire safety of ancient buildings due to their excellent decorative properties and fire resistance properties. Phosphorus-based flame retardants are widely applied as the main component of transparent fire- retardant coatings due to the advantages of environmental friendliness, high efficiency, low toxicity, etc.. This paper summarizes the research progress of phosphorus-based flame retardants in transparent fire-retardant coatings from the aspects of phosphate ester flame retardants, phosphorus-nitrogen flame retardants and composite phosphorus flame retardant. Research pointed out that the development of multifunctional modified phosphorus flame retardants, the realization of three sources in one, organic and inorganic phosphorus flame retardants, and the synergistic flame retardancy of multiple elements are the development trend of transparent fireretardant coatings in the future.

Key words: transparent fire- retardant coating, phosphate ester flame retardants, phosphorus-nitrogen flame retardant, composite phosphorus flame retardant

胡肖, 颜龙, 黄傲, 赵敏, 王学宝, 孙均利, 王霁. 磷系阻燃剂在透明防火涂料中的应用研究进展[J]. 消防科学与技术, 2021, 40(7): 1061-1064.

HU Xiao, YAN Long, HUANG Ao, ZHAO Min, WANG Xue-bao, SUN Jun-li, WANG Ji. Progress in research and application of phosphorous flame retardants in transparent fire-retardant coatings[J]. Fire Science and Technology, 2021, 40(7): 1061-1064.