主管：中华人民共和国应急管理部
主办：应急管理部天津消防研究所
ISSN 1009-0029  CN 12-1311/TU
消防科学与技术

消防科学与技术 ›› 2025, Vol. 44 ›› Issue (8): 1130-1135.

• • 上一篇    下一篇

聚苯胺改性玄武岩在防腐防火涂层中的应用

余华龙, 金义杰, 陈奡, 贾丹   

  1. （中国机械总院集团武汉材料保护研究所有限公司 特种表面保护材料及应用技术国家重点实验室，湖北 武汉 430030）
  • 收稿日期:2024-07-22 修回日期:2024-10-24 出版日期:2025-08-15 发布日期:2025-08-15
  • 作者简介:余华龙，中国机械总院集团武汉材料保护研究所有限公司工程师，硕士，主要从事功能涂层材料的开发与应用研究，湖北省武汉市硚口区宝丰二路126号，430030。
  • 基金资助:
    国家自然科学基金项目（5220521）

Application of polyaniline modified basalt in anti-corrosion and fire-retardant coatings

Yu Hualong, Jin Yijie, Chen Ao, Jia Dan   

  1. (State Key Laboratory of Special Surface Protection Materials and Application Technology, China Academy of Machinery Wuhan Research Institute of Materials Protection Co., Ltd., Wuhan Hubei 430030, China)
  • Received:2024-07-22 Revised:2024-10-24 Online:2025-08-15 Published:2025-08-15

摘要： 为满足钢结构防腐防火一体化需求，结合聚苯胺的钝化防腐功能以及玄武岩鳞片的阻隔屏蔽作用，采用原位聚合方法制备了聚苯胺（PANI）改性玄武岩鳞片（BS）复合材料（PANI-BS）。对复合材料的形貌、组成和结构进行分析，并考察了该复合材料在水性环氧体系中的协同防腐蚀以及防火隔热性能。结果表明：通过草酸掺杂和原位聚合成功制备了PANI修饰改性的BS，PANI-BS在纯环氧体系中具有良好的防腐蚀功能，通过搭配三元阻燃膨胀剂制备的环氧防火涂层也展现出良好的防火隔热性能。涂层综合性能与PANI-BS添加量相关，其中，含3%复合材料的涂层具有最佳的防腐防火能力。试验表明，PANI-BS在防腐防火一体化中具有良好的应用潜力。

关键词: 膨胀型防火涂料, 聚苯胺, 玄武岩鳞片, 防腐防火

Abstract: In order to meet the integrated requirements of anti-corrosion and fire prevention for steel structures, by leveraging the passivation anti-corrosion function of polyaniline and the barrier shielding effect of basalt scales, polyaniline (PANI) modified basalt flakes (BS) composite material (PANI-BS) was prepared by in-situ polymerization method. The morphology, composition and structure of the composite material were analyzed， and the synergistic anti-corrosion and fire resistance properties of the composite material in waterborne epoxy system were investigated. Results showed that PANI coated modified BS can be obtained through oxalic acid doping and in-situ polymerization. PANI-BS has good anti-corrosion function in pure epoxy system, and the epoxy fireproof coating prepared by combining with ternary flame retardant expansion agent also exhibits good fire resistance performance. The comprehensive performance of the coating is related to the amount of PANI-BS added, and the coating containing 3% composite material has the best anti-corrosion and fireproof ability. The experiment shows that PANI-BS has good potential for application in the integration of anti-corrosion and fire prevention requirements.

Key words: intumescent coatings, polyaniline, basalt scales, anti-corrosion and fire-resistant