主管:中华人民共和国应急管理部
主办:应急管理部天津消防研究所
ISSN 1009-0029  CN 12-1311/TU

消防科学与技术 ›› 2023, Vol. 42 ›› Issue (6): 808-811.

• • 上一篇    下一篇

改性蒙脱土对硅胶泡沫复合材料性能影响研究

刘博, 王春雨, 冀贤, 宫花   

  1. (西安科技大学 安全科学与工程学院,陕西 西安 710054)
  • 出版日期:2023-06-15 发布日期:2023-06-15
  • 作者简介:作者简介:刘博(1986- ),女,西安科技大学安全科学与工程学院副教授,博士,主要从事阻燃材料的研究,陕西省西安市西雁塔中路58号,710054。
  • 基金资助:
    国家自然科学基金(51904233);陕西省教育厅青年创新团队建设科研计划项目(21JP076);陕西省创新能力支撑计划项目(2020TD-021)

Effect of modified montmorillonite on properties of silicone rubber foam composites

Liu Bo, Wang Chunyu, Ji Xian, Gong Hua   

  1. (College of Safety Science and Engineering, Xi'an University of Science and Technology, Shaanxi Xi'an 710054, China)
  • Online:2023-06-15 Published:2023-06-15

摘要: 采用高温硫化法制备了4种改性蒙脱土/硅橡胶泡沫复合材料(SiFs),对含有不同改性蒙脱土的硅橡胶泡沫复合材料开展了阻燃性能及力学性能研究。采用氧指数测试仪、锥形量热仪和力学拉伸仪表征SiFs的阻燃性能和力学性能。结果表明:十六烷基三甲基溴化铵改性蒙脱土(CMMT)对SiFs的阻燃性能和力学性能影响显著。添加3%质量分数的CMMT时的SiFs的极限氧指数值达到28.5%,并达到V-0级别。与纯SiF相比,添加3%质量分数的CMMT时的SiFs的断裂伸长率提升至278%,热释放峰值和总产烟量分别降低了20.8%和39%,CMMT在SiFs表面形成了致密的炭层,显著提升了SiFs的阻燃性能。

关键词: 蒙脱土, 硅橡胶泡沫, 十六烷基三甲基溴化铵, 阻燃, 抑烟

Abstract: Four kinds of modified montmorillonite/silicone rubber foam composites (SiFs) were prepared by high temperature vulcanization method. The flame retardant and mechanical properties of the silicone rubber foam composites containing different modified montmorillonite were studied. Oxygen index tester, cone calorimeter and mechanical tensile instrument were used to measure the flame retardant and mechanical properties of SiFs. The results of oxygen index tester, cone calorimeter, thermogravimetric analyzer and mechanical tensile tester show that cetyltrimethyl ammonium bromide modified montmorillonite (CMMT) has a significant effect on the flame retardancy and mechanical properties of SiFs. When the addition of CMMT is 3%,The limiting oxygen index value of SiFs reaches 28.5% and reaches V-0 level. Compared with pure SiF, the elongation at break of its increased to 278%, and the peak heat release and total smoke production decreased by 20.8% and 39% respectively. CMMT promotes the formation of dense carbon layer of SiFs, which significantly improves the flame retardancy of SiFs.

Key words: montmorillonite, silicone rubber foam, cetyltrimethylammonium bromide, flame retardant, smoke suppression