|
Thermogravimetric study of 5 tree species at different heating rates
Zhang Jinqi, Li Xiangchen, Li Xianyu, Zhou Mei
2022, 41 (12):
1732-1736.
To explore the pyrolysis characteristics of five typical tree species at different heating rates, the twigs of Betula platyphylla, Betula davurica, Larix gmelinii, Quercus mongolica and Populus simonii were taken as the main research objects. Based on OFW thermogravimetric analysis, the heating range was from 30 ℃ to 600 ℃ with oxygen as carrier gas in air atmosphere. Firstly, the temperature was raised to 100 ℃ and kept for 5 min. The gas flow rate was 20 mL/min, then the temperature was raised at 40, 60, 80 ℃/min respectively. TG-DTG curve was used to analyze the pyrolysis process of the sample, and OFW method was used to analyze the kinetics of the rapid pyrolysis stage of the sample. The results show that the effect of heating rate on the pyrolysis process is mainly concentrated in the weight loss stage. As the heating rate increases, the pyrolysis characteristic temperature increases and the weight loss rate of the sample increases. At this stage, when the heating rate was 60 ℃/min, the pyrolysis degree of five typical tree species was Larix gmelinii>Quercus mongolica>Populus davidiana>Betula platyphylla>Betula platyphylla. The activation energy of the five tree species analyzed by OFW method changed with the conversion rate. The activation energy calculation results were reliable and the model was better. The activation energy range of Populus davidiana was 659.788~712.664 kJ/mol, and the adjusted R2 range was 0.962 6~0.999 7. The activation energy decreased first and then increased with the increase of conversion rate, and good exothermic reaction was still maintained in the latter part of the reaction process.
Related Articles |
Metrics
|