主管:中华人民共和国应急管理部
主办:应急管理部天津消防研究所
ISSN 1009-0029  CN 12-1311/TU

消防科学与技术 ›› 2022, Vol. 41 ›› Issue (12): 1753-1757.

• • 上一篇    下一篇

聚氨酯泡沫热解产物对可燃液体物证鉴定的干扰性研究

许 洁1,金 静1,王昊晨2   

  1. (1.中国人民警察大学,河北 廊坊 065000; 2.马鞍山市消防救援支队,安徽 马鞍山 243000)
  • 出版日期:2022-12-15 发布日期:2022-12-16
  • 作者简介:作者简介:许 洁(1983- ),女,河北廊坊人,中国人民警察大学讲师,硕士,主要从事火灾调查及助燃剂物证鉴定研究,河北省廊坊市西昌路220号,065000。
  • 基金资助:
    :河北省自然科学基金资助项目(B2021507001);河北省教育厅项目(ZC2022091);中国人民警察大学中青年教师科研创新计划项目(ZQV2019018)

Study on identification interference of pyrolysis products of polyurethane foam on flammable liquids

Xu Jie1, Jin Jing1,Wang Haochen2   

  • Online:2022-12-15 Published:2022-12-16

摘要: 摘 要:以不同密度聚氨酯泡沫为研究对象,采用同步热分析(STA)和气相色谱-质谱联用技术(GC-MS),分析了聚氨酯泡沫塑料热解产物对汽油鉴定干扰性的影响。试验表明,聚氨酯泡沫塑料热解过程可分为两个阶段,80 kg/m3聚氨酯泡沫塑料第一阶段热解初始温度略低,质量损失率略大。聚氨酯泡沫塑料燃烧残留物中可检测到芳香烃、稠环芳烃和茚满类特征组分,但40 kg/m3聚氨酯泡沫塑料燃烧残留物检出的相似特征组分数量明显较多,因此,40 kg/m3聚氨酯泡沫塑料对汽油鉴定的干扰性高于80 mg/m3。

关键词: 关键词:气相色谱-质谱仪, 同步热分析仪, 聚氨酯泡沫塑料, 汽油, 热解, 易燃液体鉴定

Abstract: In this paper, the pyrolysis characteristics of polyurethane foams with different densities and their influence on gasoline identification were analyzed by simultaneous thermal analysis(STA)and gas chromatography-mass spectrometry(GC-MS).Experiments result indicated that there are two main weight loss processes during the thermal decomposition of polyurethane foams. In the first stage, the initial pyrolysis temperature of 80 kg/m3 polyurethane foam is slightly lower and the mass loss rate is slightly larger. The target characteristic components of aromatic hydrocarbons, polycyclic aromatic hydrocarbons and Indane gasoline can be detected in the combustion residue of polyurethane foam, but the number of characteristic components detected in the combustion residue of 40 kg/m3 polyurethane foam is obviously higher, so the 40 kg/m3 The research results provide some data support for the identification of flammable liquids.density polyurethane foam has stronger interference than 80 kg/m3 in gasoline identification.

Key words: gas chromatography-mass spectrometer, synchronous thermal analyzer, polyurethane foam, gasoline, pyrolysis, identification of flammable liquids